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[parent] Dalton's law (Derivation)

The gases are mixable with each other in all proportions.  Since the ideal gas law

$\displaystyle pV = nRT$ (1)
is valid for any ideal gas, one may think that it's insignificant whether the mole number $n$ concerns one single gas or several gases.  It is true, which can be shown experimentally.

Let's think that we mix the volumes $V_1$, $V_2$, ..., $V_k$ of different gases having an equal pressure $p$ and an equal temperature $T$.  If one measures the volume $V$ of the mixture in the same pressure and temperature, one notices that

$\displaystyle V = V_1\!+\!V_2\!+\!...\!+\!V_k.$
Each of the gases satisfies an equation  $pV_i = n_iRT$,  and thus
$\displaystyle pV = pV_1\!+\!pV_2\!+\!...\!+\!pV_k = (n_1\!+\!n_2\!+\!...\!+\!n_k)RT.$ (2)
This is similar as the general equation (1).  If we think that the same volume $V$ would be filled by any of the gases alone, we had an equation

$\displaystyle p_iV = n_iRT$
for each gas; here the pressure $p_i$, i.e. $n_i\frac{RT}{V}$, is called the partial pressure of the gas $i$.  By (2), we have

$\displaystyle p = (n_1\!+\!n_2\!+\!...\!+\!n_k)\frac{RT}{V} = n_1\frac{RT}{V}\!+\!n_2\frac{RT}{V}\!+\!...\!+\!n_k\frac{RT}{V} = p_1\!+\!p_2\!+\!...\!+\!p_k.$
Accordingly we have obtained the

Dalton's law.  The pressure of a gas mixture is equal to the sum of the partial pressures of the component gases.

This law was invented by J. Dalton in 1801.



"Dalton's law" is owned by pahio.

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Also defines:  partial pressure

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Cross-references: temperature, volumes, ideal gas law
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This is version 3 of Dalton's law, born on 2006-06-02, modified 2006-06-03.
Object id is 182, canonical name is DaltonsLaw.
Accessed 1917 times total.

Classification:
Physics Classification51.30.+i (Thermodynamic properties, equations of state )
 51.35.+a (Mechanical properties; compressibility)

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